Articles

What is the combustion mechanism of fuels?

  1. Controlling steps for the three fuel types

Gaseous fuels: mainly gas-phase reactions; process = mixing + chemical reaction; control often by mixing rate (diffusion flame) or reaction kinetics (premixed flame).

Liquid fuels: atomize into droplets -> evaporate -> mix with air -> gas-phase combustion. Control often by atomization quality (droplet size) and evaporation rate.

Solid fuels (coal/coke):

  • Volatiles release and burn (gas phase)
  • Solid carbon (coke) surface reactions: C+O2CO2C+O_2\to CO_2, oxygen-deficient: 2C+O22CO2C+O_2\to 2CO
    Control often by coupled heat/mass transfer (oxygen diffusion, ash-layer diffusion) and kinetics.
  1. Typical reaction network (simplified)
  • C+O2CO2C+O_2\to CO_2
  • 2C+O22CO2C+O_2\to 2CO
  • CO+12O2CO2CO+\tfrac12 O_2\to CO_2
  • H2+12O2H2OH_2+\tfrac12 O_2\to H_2O
  • S+O2SO2S+O_2\to SO_2
  1. Complete vs incomplete combustion
    Complete combustion: all combustibles convert to stable oxides (CO2,H2O,SO2CO_2,H_2O,SO_2). Incomplete combustion shows COCO, unburned hydrocarbons, soot, and higher carbon in fly ash; corresponding heat losses increase.